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By M. de Cuyper

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24 Biomimetic materials synthesis Other inorganic particles synthesised in phospholipid vesicles include selenides [70], mixed semiconductors [71], Al2O3 [72] and AI2O3 nano-composites with other metal oxides/hydroxides [73], Au and Co metals [74], as well as magnetic iron oxides [75]. 2. 2. I. Surfactant monolayers and Langmuir-Blodgett films Surfactant molecules, spread on a water surface, align themselves such that the ionic (or polar) part of the molecule interacts with the water while the hydrocarbon tail is oriented away from the surface.

1. Synthesis of Zerovalent Copper Nanoclusters, J. Am. Chem. Soc. 120, 7355-7356. , Crooks, R. M. (1998) Preparation of Cu Nanoclusters within Dendrimer Templates, J. Am. Chem. SOC. 120, 4877-4878. 30. Garcia, M. , Baker, L. A,, Crooks, R. M. (1999) Preparation and characterisation of dendrimer-gold colloid nanocomposites, Anal. Chem. 71, 256-258. , Crooks, R. M. (1999) Dendrimer-encapsulated Pt nanoparticles. Synthesis, characterisation, and applications to catalysis, Adv. Muter. ) 11, 217-220.

Surfactant monolayers were shown to organise pre-formed nanoparticles into ordered arrays. Dispersion of colloid suspensions of particles on aqueous sub-phase in a Langmuir film balance produced monoparticulate films of TiO2 [90], Fe3O4 [91] and precious metals [92]. e. three-dimensional template of amphiphile molecules may be used for the growth of inorganic nanoparticles in a 3-D array. For example, multilayers of cadmium alkanoates can nucleate cadmium sulphide nanocrystals on the exposure to H2S [93].

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