By Bard A.J., Stratmann M., Schafer H.J.
Writing for pros in addition to scholars, editors Schafer (chemistry, U. of Munster), Bard (chemistry, U. of Texas at Austin), Stratmann (corrosive technology and floor engineering, U, of Erlangen) and individuals learn quite a lot of issues in the box of natural electrochemistry, together with study on functions in different fields comparable to inorganic and natural compounds and organic structures. Article issues contain how to examine mechanisms of electroorganic reactions; functional features of preparative scale electrolysis; comparisons of chemical and electrochemical tools in natural synthesis; catholic reactions of hydrocarbons, olefins, and fragrant compounds; anodic reactions of alkanes, alkenes, and fragrant compounds; oxidation (and aid) of oxygen-containing compounds, and of halogen-containing compounds; electrochemistry of nitrogen-containing compounds; electrosynthesis of usual items, fantastic chemical compounds, and prescribed drugs; electrochemistry of heterocycles; selectivity in electrochemical reactions; electrogenerated acids and bases; oblique electrochemical reactions; and engaging in polymers.
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Additional resources for Encyclopedia of Electrochemistry, Organic Chemistry
An optimally perforated structure of the electrode is desired, for example, expanded metal sheets. A horizontal electrode arrangement can be suitable for undivided cells or if a gas evolution only is possible at the upper electrode. If there is a formation of gas at both electrodes in divided cells, mostly vertical electrodes will be necessary. Then a possible decrease of the current density in the upper part of the cell has to be considered (see Sect. 1). 3 Gas Diffusion Electrodes Gas diffusion electrodes (GDE’s) are well known from fuel cells, for example, .
Usually, it is also applied in industrial scale electrolysis. For laboratory scale experiments, inexpensive power supplies for constant current operation are available (also a potentiostat normally can work in galvanostatic operation). The transferred charge can be calculated directly by multiplication of cell current and time (no integration is needed). The electrode potentials (exactly the overvoltages) are dependant on the current density. Thus, using the galvanostatic operation mode, optimal results are attained only if a well-deﬁned current density can be chosen with a clear difference between desired and undesired reactions, as in Fig.
Usually, these concentration differences increase proportional to the current density, according to the ﬁrst Fick’s law. 3 Limiting Current Density The diffusion overvoltage hinders the current density to rise continuously with increasing potential, especially in case of low reactant concentrations. The ‘‘limiting current density’’ for a reaction is reached when the current density becomes equivalent to the maximally accessible diffusion rate of a required reactant, see the horizontal sections of the thick curves in Fig.